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Journal Articles

Recovery of alkali salt by supercritical fluid leaching method using carbon dioxide

Watanabe, Takeshi*; Tsushima, Satoru*; Yamamoto, Ichiro*; Tomioka, Osamu; Meguro, Yoshihiro; Nakashima, Mikio; Wada, Ryutaro*; Nagase, Yoshiyuki*; Fukuzato, Ryuichi*

Proceedings of 2nd International Symposium on Supercritical Fluid Technology for Energy and Environment Applications (Super Green 2003), p.363 - 366, 2004/00

Recovery of salts by supercritical fluid leaching (SFL) method using carbon dioxide was experimentally studied. It was confirmed that LiCl was recovered with a mixed fluid of carbon dioxide and methanol, and KCl and SrCl$$_2$$ were recovered with a mixed fluid of carbon dioxide, methanol and crown ether. The influence of crown ether for KCl and SrCl$$_2$$ extraction were found to increase in the order of 15-crown-5 (15C5) $$<$$ 18-crown-6 (18C6) $$<$$ dicychlohexyl-18-crown-6 (DC18C6). It is expected that other salts can be recovered selectively with a mixed fluid of carbon dioxide, methanol and suitable crown ether.

Journal Articles

Development of radioactive waste treatment by Supercritical Fluid Leaching (SFL) method

Nagase, Yoshiyuki*; Masuda, Kaoru*; Wada, Ryutaro*; Yamamoto, Ichiro*; Tomioka, Osamu; Meguro, Yoshihiro; Fukuzato, Ryuichi*

Proceedings of 2nd International Symposium on Supercritical Fluid Technology for Energy and Environment Applications (Super Green 2003), p.254 - 257, 2004/00

no abstracts in English

JAEA Reports

None

Nomura, Kazunori; *; *; Koyama, Tomozo; *; *;

PNC TN8410 96-206, 33 Pages, 1996/07

PNC-TN8410-96-206.pdf:1.43MB

None

Journal Articles

Cerenkov counting method for Sr-89/90 determination in fission product Mo-99

Genka, Tsuguo; A.Mutalib*; H.I.Komala*; M.Ramli*; Adang.H.G.*; M.Sayad*; E.Sovilawati*; W.R.Suparna*

Kinrin Ajia Shokoku Niokeru Genshiryoku Anzen Kakuho Suijun Chosa Hokokusho, 0, p.254 - 266, 1996/02

no abstracts in English

JAEA Reports

None

Nomura, Kazunori; ; ; ;

PNC TN8410 95-286, 20 Pages, 1995/11

PNC-TN8410-95-286.pdf:1.07MB

None

JAEA Reports

None

; ;

PNC TN8420 95-022, 228 Pages, 1995/10

PNC-TN8420-95-022.pdf:7.59MB

None

Journal Articles

Synergistic ion-pair extraction of lanthanide(III) with thenoyltrifluoroacetone and crown ether into 1,2-dichloroethane

Kitatsuji, Yoshihiro; Meguro, Yoshihiro; Yoshida, Zenko; *; *

Solvent Extr. Ion Exch., 13(2), p.289 - 300, 1995/00

 Times Cited Count:64 Percentile:90.84(Chemistry, Multidisciplinary)

no abstracts in English

Journal Articles

Synergistic ion-pair extraction of Am(III) and Cm(III) by thenoyltrifluoroacetone and crown ether

Meguro, Yoshihiro; Yoshida, Zenko

Radiochimica Acta, 65, p.19 - 22, 1994/00

no abstracts in English

JAEA Reports

None

PNC TJ1600 93-005, 66 Pages, 1993/03

PNC-TJ1600-93-005.pdf:1.96MB

no abstracts in English

Oral presentation

Preparation of crown ether derivative-impregnated Sr-adsorptive fibers for rapid analysis of Sr-90

Konda, Miki; Asai, Shiho; Hanzawa, Yukiko; Saito, Kyoichi*; Fujiwara, Kunio*; Sugo, Takanobu*; Magara, Masaaki

no journal, , 

The concentration of $$^{90}$$Sr is normally determined with a beta counter, which involves time-consuming pretreatment procedures. To minimize such pretreatment procedures, an adsorbent achieving high-speed separation would be helpful. Adsorbents prepared by graft polymerization have an ideal surface structure, promoting efficient adsorption of analytes to functional groups of the polymer chain attached through the polymerization reaction. In this study, an extractant for Sr$$^{2+}$$, dicyclohexano-18-crown-6 (DC8C6) was impregnated onto alkylamino-group-introduced graft chains based on hydrophobic interaction. A nylon fiber was employed as a base polymer, which allows to form various shapes according to measurement modes. The amount of impregnated DC8C6 is comparable to those of commercially available Sr adsorbents. This indicates that the prepared fibers have an adequate adsorptivity for Sr ion from a practical perspective.

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